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Latest comment: 1 month ago by Smokefoot in topic Not epoxides

Wiki Education assignment: CHEM 300

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This article was the subject of a Wiki Education Foundation–supported course assignment, between 4 September 2024 and 6 December 2024. Further details are available on the course page. Student editor(s): Eeguale, Chloeczhou (article contribs). Peer reviewers: Mhodgkin17, Carbon20, Keirav, Nidhidanda28.

— Assignment last updated by SwangoPrism (talk) 01:50, 11 November 2024 (UTC)Reply

Not epoxides

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At least this editor does not include epoxides in discussions of ethers. A debatable issue. To that end, the following was removed from the article: "Perfluorinated [[epoxide]]s can be used as used as [[comonomer]]s for the production of [[polytetrafluoroethylene]] (PTFE).<ref name=":2">{{Cite book |last1=Siegemund |first1=Günter |title=Ullmann's Encyclopedia of Chemical Technology |last2=Schwertfeger |first2=Werner |last3=Feiring |first3=Andrew |last4=Smart |first4=Bruce |last5=Behr |first5=Fred |last6=Vogel |first6=Herward |last7=McKusick |first7=Blaine |last8=Kirsch |first8=Peer |date=2016-01-28 |publisher=Wiley-VCH Verlag GmbH & Co. KGaA |isbn=978-3-527-30673-2 |location=Weinheim, Germany |pages=1–56 |language=en |chapter=Fluorine Compounds, Organic |doi=10.1002/14356007.a11_349.pub2}}</ref> [[File:Hexafluoropropylene_oxide.png|thumb|[[Hexafluoropropylene oxide]] (HFPO), a type of perfluorinated epoxide.]] Perfluorinated epoxides are a class of epoxides where all the hydrogen atoms on a carbon chain are replaced with fluorine atoms. The fluorine ensures compatibility with PTFE, while the epoxy group enables chemical bonding during [[polymerization]]. When used as comonomers, they can alter the microstructure of PTFE, reducing [[crystallinity]] and improving flexibility and toughness. This makes the polymer more suitable for applications like seals and gaskets, which require resilience under stress. Furthermore, perfluorinated epoxides enable the tailoring of specific functional properties, such as low [[surface energy]], which is essential for applications requiring non-stick or low-friction surfaces.<ref name=":2" /><ref>{{Cite journal |last1=Cı́rkva |first1=Vladimı́r |last2=Gaboyard |first2=Manuel |last3=Paleta |first3=Oldřich |date=2000-03-01 |title=Fluorinated epoxides: 5. Highly selective synthesis of diepoxides from α,ω-diiodoperfluoroalkanes. Regioselectivity of nucleophilic epoxide-ring opening and new amphiphilic compounds and monomers |url=https://www.sciencedirect.com/science/article/abs/pii/S0022113999003012 |journal=Journal of Fluorine Chemistry |volume=102 |issue=1 |pages=349–361 |doi=10.1016/S0022-1139(99)00301-2 |bibcode=2000JFluC.102..349C |issn=0022-1139|url-access=subscription }}</ref>"--Smokefoot (talk) 23:00, 24 August 2026 (UTC)Reply